http://www.empireonline.com/news/story.asp?NID=44240

Marvel has released a start-of-shoot notice that includes the expected folk (Iron Man, Black Widow and, oh yes, the slightly important Captain America), but also some that had only been rumoured until now, including The Vision (Paul Bettany), Hawkeye (Jeremy Renner), James “War Machine” Rhodes (Don Cheadle) and, perhaps more surprisingly, Ant-Man (Paul Rudd), who doesn't make his MCU debut until later this year.

And that’s far from all. The film will wrangle together Sebastian Stan’s Bucky Barnes/The Winter Soldier, Anthony Mackie’s Sam Wilson/The Falcon, Elizabeth Olsen’s Scarlet Witch, Frank Grillo as Brock Rumlow from the second Cap film, who will return as villain Crossbones, Chadwick Boseman as Black Panther, Emily VanCamp as Sharon “Agent 13” Carter, Daniel Bruhl as baddie Baron Zemo and Martin Freeman in a still-unconfirmed role.
 
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