You guys were right about Band 41...Jio doesn't posses band 41 anywhere in India?
Found out the reason for above.....
Actually Redmi Note 5 pro has old version of Android, it was displaying information of both the sim even when only 1 SIM was selected. While Realme 6i had Android 11 and Redmi Note 7 pro had Android 10 and displayed information about SIM 1's primary band only.
And the 2nd SIM on Redmi Note 5 pro is Vodafone, hence Band 41..... you can tell by MCC MNC code.
Sorry for that...